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Saturday, August 16, 2008

Nanotechnology :Applications of Nanomaterials


Below we list some key current and potential shortand long-term applications of nanomaterials. Most current applications represent evolutionary developments of existing technologies: for example, the reduction in size of electronics devices.

Current Applications
a) Sunscreens and Cosmetics
Nanosized titanium dioxide and zinc oxide are currently used in some sunscreens, as they absorb and reflect ultraviolet (UV) rays and yet are transparent to visible light and so are more appealing to the consumer. Nanosized iron oxide is present in some lipsticks as a pigment but it is our understanding that it is not used by the European cosmetics sector. The use of nanoparticles in cosmetics has raised a number of concerns about consumer safety.
b) Composites
An important use of nanoparticles and nanotubes is in composites, materials that combine one or more separate components and which are designed to exhibit overall the best properties of each component. This multi-functionality applies not only to mechanical properties, but extends to optical, electrical and magnetic ones. Currently, carbon fibres and bundles of multi-walled CNTs are used in polymers to control or enhance conductivity, with applications such as antistatic packaging. The use of individual CNTs in composites is a potential long-term application. A particular type of nanocomposite is where nanoparticles act as fillers in a matrix; for example, carbon black used as a filler to reinforce car tyres. However, particles of carbon black can range from tens to hundreds of nanometres in size, so not all carbon black falls within our definition of nanoparticles.
c) Clays
Clays containing naturally occurring nanoparticles have long been important as construction materials and are undergoing continuous improvement. Clay particle based composites – containing plastics and nano-sized flakes of clay – are also finding applications such as use in car bumpers.
d) Coatings and Surfaces
Coatings with thickness controlled at the nano- or atomic scale have been in routine production for some time, for example in molecular beam epitaxy or metal oxide chemical vapor depositionfor optoelectonic devices, or in catalytically active and chemically functionalized surfaces. Recently developed applications include the self-cleaning window, which is coated in highly activated titanium dioxide, engineered to be highly hydrophobic (water repellent) and antibacterial, and coatings based on nanoparticulate oxides that catalytically destroy chemical agents. Wear and scratch-resistant hard coatings are significantly improved by nanoscale intermediate layers (or multilayers) between the hard outer layer and the substrate material. The intermediate layers give good bonding and graded matching of elastic and thermal properties, thus improving adhesion. A range of enhanced textiles, such as breathable, waterproof and stainresistant fabrics, have been enabled by the improved control of porosity at the nanoscale and surface roughness in a variety of polymers and inorganics.
e) Tougher and Harder Cutting Tools
Cutting tools made of nanocrystalline materials, such as tungsten carbide, tantalum carbide and titanium carbide, are more wear and erosion-resistant, and last longer than their conventional (large-grained) counterparts. They are finding applications in the drills used to bore holes in circuit boards.
Short-term Applications (next 5 years)a) Paints
Incorporating nanoparticles in paints could improve their performance, for example by making them lighter and giving them different properties. Thinner paint coatings (‘lightweighting’), used for example on aircraft, would reduce their weight, which could be beneficial to the environment. However, the whole life cycle of the aircraft needs to be considered before overall benefits can be claimed. It may also be possible to substantially reduce solvent content of paints, with resulting environmental benefits. New types of foulingresistant marine paint could be developed and are urgently needed as alternatives to tributyl tin (TBT), now that the ecological impacts of TBT have been recognised. Anti-fouling surface treatment is also valuable in process applications such as heat exchange, where it could lead to energy savings. If they can be produced at sufficiently low cost, fouling-resistant coatings could be used in routine duties such as piping for domestic and industrial water systems. It remains speculation whether very effective anti-fouling coatings could reduce the use of biocides, including chlorine. Other novel, and more long-term, applications for nanoparticles might lie in paints that change colour in response to change in temperature or chemical environment, or paints that have reduced infra-red absorptivity and so reduce heat loss.
Concerns about the health and environmental impacts of nanoparticles may require the need for the durability and abrasion behaviour of nano-engineered paints and coatings to be addressed, so that abrasion products take the form of coarse or microscopic agglomerates rather than individual nanoparticles.
b) Remediation
The potential of nanoparticles to react with pollutants in soil and groundwater and transform them into harmless compounds is being researched. In one pilot study the large surface area and high surface reactivity of iron nanoparticles were exploited to transform chlorinated hydrocarbons (some of which are believed to be carcinogens) into less harmful end products in groundwater. It is also hoped that they could be used to transform heavy metals such as lead and mercury from bioavailable forms into insoluble forms. Serious concerns have been raised over the uncontrolled release of nanoparticles into the environment.
c) Fuel Cells
Engineered surfaces are essential in fuel cells, where the external surface properties and the pore structure affect performance. The hydrogen used as the immediate fuel in fuel cells may be generated from hydrocarbons by catalytic reforming, usually in a reactor module associated directly with the fuel cell. The potential use of nano-engineered membranes to intensify catalytic processes could enable higher-efficiency, small-scale fuel cells. These could act as distributed sources of electrical power. It may eventually be possible to produce hydrogen locally from sources other than hydrocarbons, which are the feedstocks of current attention.
d) Displays
The huge market for large area, high brightness, flat-panel displays, as used in television screens and computer monitors, is driving the development of some nanomaterials. Nanocrystalline zinc selenide, zinc sulphide, cadmium sulphide and lead telluride synthesized by sol–gel techniques (a process for making ceramic and glass materials, involving the transition from a liquid ‘sol’ phase to a solid ‘gel’ phase) are candidates for the next generation of light-emitting phosphors. CNTs are being investigated for low voltage field-emission displays; their strength, sharpness, conductivity and inertness make them potentially very efficient and long-lasting emitters.
e) Batteries
With the growth in portable electronic equipment (mobile phones, navigation devices, laptop computers, remote sensors), there is great demand for lightweight, high-energy density batteries. Nanocrystalline materials synthesized by sol–gel techniques are candidates for separator plates in batteries because of their foam-like (aerogel) structure, which can hold considerably more energy than conventional ones. Nickel–metal hydride batteries made of nanocrystalline nickel and metal hydrides are envisioned to require less frequent recharging and to last longer because of their large grain boundary (surface) area.
f) Fuel Additives
Research is underway into the addition of nanoparticulate ceria (cerium oxide) to diesel fuel to improve fuel economy by reducing the degradation of fuel consumption over time.
g) Catalysts
In general, nanoparticles have a high surface area, and hence provide higher catalytic activity. Nanotechnologies are enabling changes in the degree of control in the production of nanoparticles, and the support structure on which they reside. It is possible to synthesise metal nanoparticles in solution in the presence of a surfactant to form highly ordered monodisperse films of the catalyst nanoparticles on a surface. This allows more uniformity in the size and chemical structure of the catalyst, which in turn leads to greater catalytic activity and the production of fewer byproducts. It may also be possible to engineer specific or selective activity. These more active and durable catalysts could find early application in cleaning up waste streams. This will be particularly beneficial if it reduces the demand for platinum-group metals, whose use in standard catalytic units is starting to emerge as a problem, given the limited availability of these metals.
Longer-term Applications (next 5-15 years)a) Carbon Nanotube Composites
CNTs have exceptional mechanical properties, particularly high tensile strength and light weight. An obvious area of application would be in nanotubereinforced composites, with performance beyond current carbon-fibre composites. One current limit to the introduction of CNTs in composites is the problem of structuring the tangle of nanotubes in a well-ordered manner so that use can be made of their strength. Another challenge is generating strong bonding between CNTs and the matrix, to give good overall composite performance and retention during wear or erosion of composites. The surfaces of CNTs are smooth and relatively unreactive, and so tend to slip through the matrix when it is stressed. One approach that is being explored to prevent this slippage is the attachment of chemical side-groups to CNTs, effectively to form ‘anchors’. Another limiting factor is the cost of production of CNTs. However, the potential benefits of such light, high strength material in numerous applications for transportation are such that significant further research is likely.
b) Lubricants
Nanospheres of inorganic materials could be used as lubricants, in essence by acting as nanosized ‘ball bearings’. The controlled shape is claimed to make them more durable than conventional solid lubricants and wear additives. Whether the increased financial and resource cost of producing them is offset by the longer service life of lubricants and parts remains to be investigated. It is also claimed that these nanoparticles reduce friction between metal surfaces, particularly at high normal loads. If so, they should find their first applications in high-performance engines and drivers; this could include the energy sector as well as transport. There is a further claim that this type of lubricant is effective even if the metal surfaces are not highly smooth. Again, the benefits of reduced cost and resource input for machining must be compared against production of nanolubricants. In all these applications, the particles would be dispersed in a conventional liquid lubricant; design of the lubricant system must therefore include measures to contain and manage waste.

c) Magnetic Materials

It has been shown that magnets made of nanocrystalline yttrium–samarium–cobalt grains possess unusual magnetic properties due to their extremely large grain interface area (high coercivity can be obtained because magnetization flips cannot easily propagate past the grain boundaries). This could lead to applications in motors, analytical instruments like magnetic resonance imaging (MRI), used widely in hospitals, and microsensors. Overall magnetisation, however, is currently limited by the ability to align the grains’ direction of magnetisation.
Nanoscale-fabricated magnetic materials also have applications in data storage. Devices such as computer hard disks depend on the ability to magnetize small areas of a spinning disk to record information. If the area required to record one piece of information can be shrunk in the nanoscale (and can be written and read reliably), the storage capacity of the disk can be improved dramatically. In the future, the devices on computer chips which currently operate using flows of electrons could use the magnetic properties of these electrons, called spin, with numerous advantages. Recent advances in novel magnetic materials and their nanofabrication are encouraging in this respect.
d) Medical Implants
Current medical implants, such as orthopaedic implants and heart valves, are made of titanium and stainless steel alloys, primarily because they are biocompatible. Unfortunately, in some cases these metal alloys may wear out within the lifetime of the patient. Nanocrystalline zirconium oxide (zirconia) is hard, wearresistant, bio-corrosion resistant and bio-compatible. It therefore presents an attractive alternative material for implants. It and other nanoceramics can also be made as strong, light aerogels by sol–gel techniques. Nanocrystalline silicon carbide is a candidate material for artificial heart valves primarily because of its low weight, high strength and inertness.
e) Machinable Ceramics
Ceramics are hard, brittle and difficult to machine. However, with a reduction in grain size to the nanoscale, ceramic ductility can be increased. Zirconia, normally a hard, brittle ceramic, has even been rendered superplastic (for example, able to be deformed up to 300% of its original length). Nanocrystalline ceramics, such as silicon nitride and silicon carbide, have been used in such automotive applications as high-strength springs, ball bearings and valve lifters, because they can be easily formed and machined, as well as exhibiting excellent chemical and high-temperature properties. They are also used as components in high-temperature furnaces. Nanocrystalline ceramics can be pressed into complex net shapes and sintered at significantly lower temperatures than conventional ceramics.
f) Water Purification
Nano-engineered membranes could potentially lead to more energy-efficient water purification processes, notably in desalination by reverse osmosis. Again, these applications would represent incremental improvements in technologies that are already available. They would use fixed nanoparticles, and are therefore distinct from applications that propose to use free nanoparticles.
g) Military Battle Suits
Enhanced nanomaterials form the basis of a state-of- the-art ‘battle suit’ that is being developed by the Institute of Soldier Nanotechnologies at MIT. A short-term development is likely to be energy-absorbing materials that will withstand blast waves; longer-term are those that incorporate sensors to detect or respond to chemical and biological weapons (for example, responsive nanopores that ‘close’ upon detection of a biological agent). There is speculation that developments could include materials which monitor physiology while a soldier is still on the battlefield, and uniforms with potential medical applications, such as splints for broken bones.

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