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Thursday, February 7, 2008
Baidu, Sohu Served With New Suits By Music Companies
Baidu, the king of China’s fast-growing Internet universe, may be facing its toughest challenge yet following a fresh lawsuit, filed in a Beijing court early this week by the world’s three biggest record companies, Sony BMG Music, Warner Music and Universal Music. The trio are attempting to stop rampant music piracy.
The three record companies are asking the court to order Baidu to remove all links on its music delivery service to copyright-infringing tracks to which they own the rights.
Baidu (nasdaq: BIDU - news - people ), whose shares are listed on Nasdaq, plummeted by as much as 9.27%, to $230, on Wednesday, marking the steepest fall amid a general decline for the day among Chinese Internet stocks listed in the United States.
Separately, Sony (nyse: SNE - news - people ) BMG, Warner Music and EMI (other-otc: EMIPY - news - people ) Music’s China affiliate, Gold Label Records, plan to take joint legal action along similar lines against popular Chinese Internet portal Sohu (nasdaq: SOHU - news - people ), which is also listed on Nasdaq, and its affiliate Sogou, a proprietary search engine, after the Chinese New Year holidays, which end on Sunday. The aim is, again, to stop the portal’s search engine from offering links to thousands of Web sites that provide unlicensed access to music downloads.
Sohu is the official sponsor of Internet content service for the upcoming Beijing Olympic Games, gaining the exclusive contract to build and host the summer Games’ official Web site. Its shares were hammered as well, dropping by 6.46% to close at $43.30 on Wednesday.
Another company, Yahoo! (nasdaq: YHOO - news - people ) China, which is operated by Alibaba (other-otc: ALBCF - news - people ), is also being served with a fresh lawsuit at the behest of the record companies' trade group, the International Federation of Phonographic Industries, for its refusal to comply with a landmark ruling in December in a higher court in Beijing, convicting it for mass copyright infringement violation against Chinese law.
None of these Chinese companies have yet responded to the new suits. The record giants were encouraged by the IFPI's December legal victory in Beijing against Yahoo! China, but they continue to be frustrated by the difficulty of making the ruling effectual in a country where law enforcement is notoriously fragile.
But the December ruling may be a harbinger of things to come. If reaffirmed, it will have broad ramifications for China’s Internet companies, Baidu above all, which have drawn heavy traffic by offering Internet users free but illegal music downloads. So popular are the music services that Google, which has been slow in catching up with Baidu in China, was reported this week in The Wall Street Journal to be in the late planning stages of a joint venture with a Chinese online music company that would permit it to provide free but licensed music downloads in China.
According to the IFPI, China has "potentially the largest online music-buying public in the world, with as many broadband connections as the United States," and the trade group reckons the market overwhelmingly consists of pirated music; around 99% of potential sales are circumvented through illegal downloading. At an aggregate size of a mere $76 million, China’s legitimate music market accounts for less than 1% of global recorded music sales, it said.
John Kennedy, chairman and chief executive of IFPI, said: "The music industry in China wants partnership with the technology companies--but you cannot build [a] partnership on the basis of systemic theft of copyrighted music and that is why we have been forced to take further actions."
more....
Google Set To Bring Free Music To China
Beijing (dbTechno) - Google may not be in the best of graces in China, but that is not stopping them from forming a joint venture with Chinese online music company, Top100.cn to bring licensed music downloads to China.
Google is heading to China to bring their free digital music market.
Google is going to sell free, licensed music downloads to people in China.
They have apparently already worked out a deal to do this with Universal, and are now in talks with Sony, and EMI.
The company has stated that every single music download will have a watermark on it so that they can trace where it goes on the web. They will also be high-quality audio files.
Google is making the move to compete with Baidu, which is popular for music searches and is still the top dog in China.
Google To Offer Free Music Downloads For Chinese UsersGoogle Inc., world’s number one Internet search engine, is targeting one of the largest online markets in the world, China, to offer free digital music downloads via the Web, the Wall Street Journal reported on Wednesday. So far, there has been one official confirmation from Universal Music, but other major labels such as EMI Group Ltd. and Sony BMG Music Entertainment are said to be in talks for the new services as well, sources familiar with the matter have said.
The Chinese music market has less of a legal side to it, while its piracy phenomenon is far more widespread than in North America and Europe. Google’s latest experiment could prove to be a lucrative deal, if the company will be able to reach an agreement with the major music labels. At the same time, Google will have to face Baidu, the number 1 Chinese search engine, currently dominating the market in the country.
“We were late entering the China market, and we’re catching up,” Google Chief Executive Eric Schmidt said last April, as the WSJ reported. “Our investment is working and we will eventually be the leader.” Baidu.com has been struggling with numerous searches for unauthorized music downloads, which has raised concerns from the music companies trying to protect their interests. Google is currently working on making quite an entrance on the Chinese online music market, with offering a free download music service.
The difference between Google’s efforts and what other competitors like Baidu Inc. and Sina Corp have to offer is that both Chinese companies have streaming music on their web sites, but they’re not downloadable. Google wants to turn that to its favor and start the new service within the next weeks. Since its debut on the Chinese market, Google came to a 26 percent market share and it’s growing stronger every year.
Broken undersea cables providing data services to parts of the Middle East and Asia should be completed by Sunday
Three undersea cables seen fixed by weekend
Repairs on two out of three broken undersea cables providing data services to parts of the Middle East and Asia should be completed by Sunday, while the third should be fixed by Saturday, cable operators said.
Undersea cable connections were disrupted off Egypt's northern coast last week when segments of two international cables were cut, affecting Internet access in the Gulf region and South Asia, and forcing service providers to re-route traffic.
A third undersea cable, FALCON, was later reported broken between Dubai and Oman.
Cable network operator FLAG Telecom, a wholly-owned unit of India's No. 2 mobile operator Reliance Communications, said on Thursday repair work on a section of the FLAG Europe-Asia cable between Egypt and Italy and on the FALCON cable system was progressing steadily and was likely to finish by February 10.
Separately, India's Videsh Sanchar Nigam Ltd, which co-owns SEA-ME-WE 4, the second cable cut near Egypt, expected repair work there to be over in a maximum of two days, a company official said.
Last Friday VSNL said it had restored a majority of its internet connectivity into the Middle East and South Asia within 24 hours of the breakdown using other SEA-ME-WE cables.
Egypt lost more than half its Internet capacity because of the breaks last week and the telecommunications ministry said last weekend it did not expect services to be back to normal for at least 10 days.
UAE telecom firm du said on Monday its Internet and telephone services were largely back to normal after it used a terrestrial cable across Saudi Arabia to circumvent the problem.
In India, Rajesh Chharia, president of the Internet Service Providers Association, said some problems remained as cable operators had not rerouted all the traffic on alternative routes.
"Lot of issues are still there till the cables are fixed," he said.
FLAG said there had been some interruption in links to London but it had transferred customers to alternate paths.
The International Cable Protection Committee, an association of 86 submarine cable operators dedicated to safeguarding submarine cables, says more than 95 percent of transoceanic telecoms and data traffic are carried by undersea cables.
Conspiracy theories abound over cut cables
Conspiracy theorists are hard at work in forums around the world, after three undersea internet cables were cut within four days.
Bloggers and commentators have fingered various governments, terrorist groups and, tongue firmly in cheek, sea-monsters, for the outages.
The drama began on 30 January when Flag Telecom detected that one of its cables between Egypt and Italy had been damaged, and worsened two days later when another running between Dubai and Oman was also cut.
The two cables together carried up to 70% of internet traffic between Europe and Asia, and their loss caused dramatic slowdowns in access from within the Middle East.
The disruption was alleviated by re-routing traffic via other routes, and is likely to be completely rectified soon as Flag Telecom's
repair ships have already reached both locations.
Initially these cuts were blamed on a ship laying anchor atop the cables in bad weather, but conspiracy theories started to emerge after the Egyptian Government claimed that no ships were present at the time.
"A marine transport committee investigated the traffic of ships in the area, 12 hours before and after the malfunction, where the cables are located to figure out the possibility of being cut by a passing vessel and found out there were no passing ships at that time," says a statement from the Egyptian Ministry of Communications and Information Technology.
On 1 February another cable, not operated by FLAG Telecom, was reportedly cut off the coast of Dubai, affecting traffic in the United Arab Emirates.
Reports of a fourth cable loss were quickly explained as a temporary power-supply problem, and swiftly rectified.
We contacted FLAG Telecom, but a spokesperson was unwilling to comment on the reason behind the failures, or how repairs were progressing.
Although it is unusual to have so many cables damaged within such a short amount of time, the first two cables lay within 400 yards of each other, so could easily have been damaged by the same event.
Microsoft Corp.'s decision to delay the availability of Windows Vista's first Service Pack
Delaying Vista SP1 unlikely to hurt corporate uptake
Six-week wait has mostly upside
It might seem that Microsoft Corp.'s decision to delay the availability of Windows Vista's first Service Pack for another six weeks due to driver problems is grounded in fear of further alienating consumers, who haven't exactly embraced the new operating system.
But Redmond's move may have been driven by a desire to appease a more important market -- business customers.
Companies typically fork out much more money per head to Microsoft than an individual consumer, through purchases of volume licenses, enterprise support contracts and Software Assurance.
As a result, they expect more.
"I would prefer Microsoft iron out the driver issues," said Sumeeth Evans, IT director for Collegiate Housing Services. The Indianapolis firm rolled out Vista to all 78 employees last year. "We are willing to wait for 6 weeks since most of our non-SP1 machines do perform pretty well."
Microsoft says that most of the drivers that break as a result of SP1 can be fixed by reinstalling them. That might be easy for an individual, but daunting to a company with scattered offices and hundreds or thousands of employees.
"It would be catastrophic for the future of Windows Vista if the Service Pack itself turned out to have major issues as well," said Lee Nicholls, global solutions director for Getronics NV, the Dutch corporate systems integrator.
If consumers have seemed slow to move to Vista, corporations have been even slower. That has as much to do with companies' satisfaction with XP as it does with their built-in conservatism.
SP1 remains a popular milestone, a signal of quality that can spur them to start an upgrade from Windows XP to Vista -- or merely the planning of one.
"We still won't see a huge boom in deployment right away, but it will at least spur plenty of companies into beginning their planning and adoption exercises," Nicholls said.
Pre-announcing SP1 thus helps spur corporations to start planning their Vista deployments. At the same time, a six-week delay in SP1's actual arrival won't matter to most companies.
IT consulting firm Avanade Inc. has been helping some large corporate clients plan for the Vista upgrade for about a year, according to Ryan McCune, a solutions director.
"In the big picture, this timing doesn't significantly affect our clients' deployment strategies or schedules," he said.
more...
What Vista's Service Pack 1 means for computer users
Microsoft has shipped the "RTM" build of Service Pack 1 of Windows Vista, meaning that those of us running this operating system soon will have some relief. The "release to manufacturing" version means that Microsoft is satisfied that this is the correct version that everyone should use, that PC makers should ship in new PCs and consumers should download.
"With Service Pack 1, we have made great progress in performance, reliability and compatibility," said Mike Nash, of Microsoft's Windows Product Management Group, in his public blog. "One of the great things about my job is that I get to play with the latest builds of our products. I've personally been running Windows Vista SP1 pretty exclusively for a few months and I've noticed that my systems run faster and more reliably than they did with the "Gold" release of Windows Vista."
Reliability is the major flaw in Vista for many corporations. Microsoft is quick to point out that it has licensed more than 100 million copies of Vista to date but that does not take into account the number of computers, including mine, that have Vista stickers on the bottom and XP on the hard drive.
Most companies won't even think of moving to Vista in the enterprise until after the first service pack so next month's consumer release is huge.
Microsoft says it bundles more than 300 patches and improvements in one bundle, which will be welcome. One of my Vista laptops, for example, won't run Windows Media Player; another won't run Word (it says the problem is caused by "Microsoft Word, a product of Microsoft Corporation" and suggests I contact them for advice.)
The biggest improvements? File copying, both locally and via a network, is up to 50 percent faster under SP1. Secondly, resuming from sleep, which is death on one of my Dell laptops, is now supposedly fixed in the new service pack.
If you're looking for new features, this is not the service pack for you.
The downside? There are some device drivers identified during the beta process that do not work well with SP1. The issue was with how the drivers were installed and not with the drivers themselves, so while Microsoft works with the vendor on a new process, the service pack simply won't install for now if it detects any of the affected drivers. (Microsoft, for now, has not released what drivers are involved.)
The Service Pack will be released via Windows Update in mid March for customers who proactively run the update. In April the Service Pack will be "pushed" to computers that have automatic updates turned on, as most computers do.
"The result is that more and more systems will automatically get SP1, but only when we are confident they will have a good experience," Nash wrote.
My recommendations have not changed. Install the Service Pack immediately when it is released but back up all of your important data first. If possible, back up your entire PC if losing all of your settings would be an inconvenience. Installing SP1 is a big deal so take it seriously.
James Derk is owner of CyberDads, a computer repair firm and tech columnist for Scripps Howard News Service. His e-mail address is jim(at)cyberdads.com
Japanese scientists plan to launch paper planes from the International Space Station to see if they make it back to Earth.
Japan scientists make paper planes for space
A spacecraft made of folded paper zooming through the skies may sound far-fetched, but Japanese scientists plan to launch paper planes from the International Space Station to see if they make it back to Earth.
On Wednesday the University of Tokyo researchers tested small, origami planes made of special paper for 30 seconds in 250 degrees Celsius (482 F) heat and wind at seven times the speed of sound. The planes survived the wind tunnel test intact.
The theory is that paper craft, being much lighter than space shuttles, may escape the worst of the friction and heat that much heavier space shuttles face on re-entry to the atmosphere.
"Paper planes are extremely light so they slow down when the air is thin and can gradually descend," said Shinji Suzuki, a professor of aerospace engineering.
Suzuki said the technology might one day be used for unmanned spacecraft.
The team has asked a Japanese astronaut to release the 20 cm (8 inches) long planes, made from paper chemically treated to resist heat and water, from the space station.
It will take several months for the craft to reach Earth and there is no way to predict their landing spot if they make it, Suzuki said.
"It's going to be the space version of a message in a bottle. It will be great if someone picks one up," he said. "We are thinking of writing messages on the planes saying 'if found, please contact us' in a couple of languages."
tec
Yahoo's CEO Says Company Still Exploring Alternatives to Microsoft's $44.6 Billion Bid
Yahoo CEO Hoping to Thwart Microsoft
Yahoo Inc. Chief Executive Jerry Yang told employees Wednesday that the struggling Internet pioneer is still examining ways to avoid a takeover by rival Microsoft Corp.
"Our board is thoughtfully evaluating a wide range of potential strategic alternatives in what is a complex and evolving landscape," Yang wrote in an e-mail. He emphasized no decision had been made on Microsoft's six-day-old bid, initially valued at $44.6 billion, or $31 per share.
Yang, who helped conceive Yahoo in 1994, didn't set a timetable for the Sunnyvale-based company's response, writing that the board "is going to take the time it needs to do it right."
Most of Wednesday's e-mail, filed with the Securities and Exchange Commission, tried to cheer up Yahoo's employees, many of whom are likely to lose their jobs in the months ahead, one way or the other.
Yahoo already has drawn up plans to trim 1,000 jobs from a 14,300-employee payroll in an effort to boost its sagging profits. The layoffs are expected to be even more severe if Microsoft devours the company because about $1 billion in expenses would be cut in a takeover. And if Yahoo were to eschew Microsoft in favor of a debt-laden leveraged buyout, about 4,500 employees could be fired, estimated Stifel Nicolaus analyst George Askew.
"We have a lot to be excited about and there's more good news to come," Yang wrote in his e-mail. He cited a shake-up of Yahoo's online music service announced earlier this week and plans to unveil new products at a mobile conference in Barcelona next week.
If Yahoo rejects Microsoft, most analysts believe the company will have to line up another acquisition offer or make radical changes to satisfy disillusioned shareholders.
But most analysts doubt any other potential suitor will have the financial muscle or desire to try to outbid Microsoft, which has $21 billion in cash and a market value of nearly $265 billion.
Yahoo could boost its profits dramatically by turning over the responsibility of running its search engine and an adjoining advertising platform to rival Google Inc., the Internet's most prosperous company.
Google CEO Eric Schmidt reportedly has broached a potential partnership with Yang, but that alliance might be blocked by antitrust regulators worried about the competitive fallout if two of the Internet's biggest ad networks join forces. Antitrust laws almost certainly preclude Google from trumping Microsoft's bid in an attempt to buy Yahoo outright.
Former Yahoo employees who know Yang have no doubt he is exhausting all avenues that might allow his company to escape Microsoft's clutches.
"Jerry bleeds purple and gold (Yahoo's corporate colors)," said Rob Solomon, a former Yahoo executive who spent six years at the company before leaving in 2006. "He always envisioned building a company that would be around for 100 years, not just 14 years."
Big vapor plume on Saturn moon
Scientists explain big vapor plume on Saturn moon.
Scientists on Wednesday said they have an explanation how one of Saturn's moons can spew out a giant plume of water vapor, adding to evidence a source of life -- water -- lies beneath the moon's frozen surface.
Using a computer model, German researchers showed the temperature at the bottom of surface cracks on Enceladus has to be about 0 degrees Celsius, the so-called triple point of water where vapor, ice and liquid water all can coexist.
"This makes this moon very interesting for further study because there is a connection between liquid water and life," Sascha Kempf, a physicist at the Max Planck Institut in Heidelberg, said in a telephone interview.
"This is the kind of thing planetary scientists hope for."
The scientists published their findings in the journal Nature.
Mars, Jupiter's moon Europa and Enceladus are the only places in the solar system with direct evidence of water. Finding organisms different from those on Earth may provide scientists with answers to questions ranging from where diseases come from to how our sun and planets formed more than 4.5 billion years ago.
Scientists have taken an especially close look at Enceladus because it seems to have a smooth surface -- suggesting recent geological activity that, in turn, could mean liquid water.
They are also intrigued by the plume itself, a gigantic geyser of water vapor and tiny ice particles. One mystery was how the dust particles slowed down to keep the plume restrained by the gravity of the moon, said Kempf, who worked on the study.
Their model showed most of the dust particles collide with the walls of the surface crack as they are ejected and constrain the gas flow to keep the plume close to the surface rather than shooting into the atmosphere, Kempf said.
The team used images of the plume and properties of the escaping gas and dust particles to run their model. They found it only reproduced the plume when the temperature was at zero degrees at the bottom of the cracks, implying water exists there in liquid form.
The density of the gas jet inside the cracks is so high that the small dust particles should have the same speeds to escape from the gravity of the moon," he said. "If this was true you wouldn't see plumes. You would see a long jets expanding into the system."
Saturn has at least 47 moons and at least seven rings. The joint U.S.-European Space Agency Cassini mission, launched in 1997, is spending four years examining Saturn.
Cassini is scheduled to fly 50 kilometers (31 miles) over the moon's surface in March, which will provide more information on the precise chemical composition of the particles and water vapor as scientists try to better understand the plume, Kempf said.
MORE..
Liquid Water Near Saturn:
Almost two weeks ago, Cassini mission scientists published a host of results pertaining to Saturn’s tiny moon Enceladus. The world had been given a hint of what to expect from the image on the right released last November that revealed a geyser of material spewing away from the south polar region of the moon. We were treated to a literal feast of fantastic results, summarized in this perspectives article by Jeffrey Kargel (a hydrologist at University of Arizona). Because of the importance of these new papers, the journal Science is offering free access to the 11 articles published in the March 10th issue relating to Cassini and Enceladus. You can spend $10 to buy the newsstand edition, gotta love free and open science!
As much as I would love to review all of the Enceladus science, so many important discoveries could not receive the attention or care they deserve in a single blog entry. Instead I will focus just on the discovery of watery geysers emanating from Enceladus’ south polar region. I will focus on the two papers detail the discovery of water ice in that jet of material, though two additional papers provide the important linkage between that jet and relatively warm surface features. The so-called tiger-stripes seen on Enceladus occur on a geologically very recent portion of the moon’s crust (Porco and others), and are shown to be about 70 degrees warmer than the surrounding crust. This makes the tiger stripes about 145 Kelvin, or -128 Celsius, while the surrounding crust is a chilly 70 Kelvin.
Synopsis
The plume picture above was taken on an Enceladus flyby last December, but three previous flybys had confirmed the presence of the plume and identified that, in fact, it was composed mostly of water ice. Two independent instruments on Cassini, the Ultraviolet-Visible-Infrared Spectrometer (UVIS) and the Ion and Neutral Mass Spectrometer (INMS), both confirmed the presence of water in the geyser.
The paper by Hansen and others describes the discovery of water in the plume using UVIS. The figure on the left shows the geometry of two flybys of Enceladus during which a sufficiently bright star was occulted by the moon. Occultations are important to astronomers and planetary scientists because in order to remotely sense the composition of an atmosphere a light source must shine through the atmosphere (more on this in the next paragraph). Part A of this figure depicts the first occultation, of the star Lambda Scorpii on the Feburary 17th, 2005 flyby. Notice that Lambda Scorpii passes behind Enceladus well above the south pole. The next occultation, of gamma Orionis (Bellatrix), occurred during the third and closest flyby on July 14th, 2005. This time, Bellatrix crossed behind the moon very near its south pole and emerged near the equator (shown in C and D).
This figure shows the spectrum of Bellatrix (blue line) along with the spectrum of light from the star seen through the plume of material near the south pole (red line). Note that prior to this detection, it was not known that Enceladus had any sort of atmosphere, even a temporary one. So the detection of absorption of the light from Bellatrix indicated that something must be happening around Enceladus.
The ratio of the red and blue lines in the previous figure are plotted in this graph as the thin solid line. Overlain on that curve as a darker solid line is the absorption spectrum of water. The water absorption spectrum explains the bulk of the total absorption seen near the south pole of Enceladus. Finer fluctuations are due to a number of a factors including the presence of other chemical species in smaller concentrations.
During the same flyby that UVIS was observing the occultation of Bellatrix by Enceladus, the INMS instrument detected something entirely unexpected: a sudden increase in particles near the south pole and surface of Enceladus. The INMS is, as its name says, a Mass Spectrometer (see this synopsis on the Huygens probe for an explanation of a similar instrument, the GCMS) that is capable of detected both ionized and neutral particles. The INMS is capable of detecting a wide range of chemicals including water, carbon dioxide, nitrogen, carbon monoxide, ammonia, and various hydrocarbons. It detected all of those compounds, some in very small quantities, in Enceladus’ plume.
The figure on the right illustrates how the density of water molecules detected by INMS changed as Cassini flew by on July 14th. A similar plume of dust was detected on the same approach using Cassini’s Cosmic Dust Analyzer (CDA). Notice that the peak of the CDA and INMS-Water plumes are offset slightly. This may indicate that the source of each plume is slightly different, or that the path between a common source and the detector differed for the dust and water. Also, notice that the peak of the water plume occurs very near to the south pole. This is strong evidence that the plume is originating from some sort of volcanic or vapor-geyser activity in that region. Combining this observation with those from UVIS and infrared maps of the surface makes a compelling case the the tiger stripes on Enceladus’ surface are the source of the plume. This, and the relatively frigid temperatures, led mission scientists to dub this plume “Cold Faithful.”
Synopsis
The plume picture above was taken on an Enceladus flyby last December, but three previous flybys had confirmed the presence of the plume and identified that, in fact, it was composed mostly of water ice. Two independent instruments on Cassini, the Ultraviolet-Visible-Infrared Spectrometer (UVIS) and the Ion and Neutral Mass Spectrometer (INMS), both confirmed the presence of water in the geyser.
The paper by Hansen and others describes the discovery of water in the plume using UVIS. The figure on the left shows the geometry of two flybys of Enceladus during which a sufficiently bright star was occulted by the moon. Occultations are important to astronomers and planetary scientists because in order to remotely sense the composition of an atmosphere a light source must shine through the atmosphere (more on this in the next paragraph). Part A of this figure depicts the first occultation, of the star Lambda Scorpii on the Feburary 17th, 2005 flyby. Notice that Lambda Scorpii passes behind Enceladus well above the south pole. The next occultation, of gamma Orionis (Bellatrix), occurred during the third and closest flyby on July 14th, 2005. This time, Bellatrix crossed behind the moon very near its south pole and emerged near the equator (shown in C and D).
This figure shows the spectrum of Bellatrix (blue line) along with the spectrum of light from the star seen through the plume of material near the south pole (red line). Note that prior to this detection, it was not known that Enceladus had any sort of atmosphere, even a temporary one. So the detection of absorption of the light from Bellatrix indicated that something must be happening around Enceladus.
The ratio of the red and blue lines in the previous figure are plotted in this graph as the thin solid line. Overlain on that curve as a darker solid line is the absorption spectrum of water. The water absorption spectrum explains the bulk of the total absorption seen near the south pole of Enceladus. Finer fluctuations are due to a number of a factors including the presence of other chemical species in smaller concentrations.
During the same flyby that UVIS was observing the occultation of Bellatrix by Enceladus, the INMS instrument detected something entirely unexpected: a sudden increase in particles near the south pole and surface of Enceladus. The INMS is, as its name says, a Mass Spectrometer (see this synopsis on the Huygens probe for an explanation of a similar instrument, the GCMS) that is capable of detected both ionized and neutral particles. The INMS is capable of detecting a wide range of chemicals including water, carbon dioxide, nitrogen, carbon monoxide, ammonia, and various hydrocarbons. It detected all of those compounds, some in very small quantities, in Enceladus’ plume.
The figure on the right illustrates how the density of water molecules detected by INMS changed as Cassini flew by on July 14th. A similar plume of dust was detected on the same approach using Cassini’s Cosmic Dust Analyzer (CDA). Notice that the peak of the CDA and INMS-Water plumes are offset slightly. This may indicate that the source of each plume is slightly different, or that the path between a common source and the detector differed for the dust and water. Also, notice that the peak of the water plume occurs very near to the south pole. This is strong evidence that the plume is originating from some sort of volcanic or vapor-geyser activity in that region. Combining this observation with those from UVIS and infrared maps of the surface makes a compelling case the the tiger stripes on Enceladus’ surface are the source of the plume. This, and the relatively frigid temperatures, led mission scientists to dub this plume “Cold Faithful.”
Synopsis
The plume picture above was taken on an Enceladus flyby last December, but three previous flybys had confirmed the presence of the plume and identified that, in fact, it was composed mostly of water ice. Two independent instruments on Cassini, the Ultraviolet-Visible-Infrared Spectrometer (UVIS) and the Ion and Neutral Mass Spectrometer (INMS), both confirmed the presence of water in the geyser.
The paper by Hansen and others describes the discovery of water in the plume using UVIS. The figure on the left shows the geometry of two flybys of Enceladus during which a sufficiently bright star was occulted by the moon. Occultations are important to astronomers and planetary scientists because in order to remotely sense the composition of an atmosphere a light source must shine through the atmosphere (more on this in the next paragraph). Part A of this figure depicts the first occultation, of the star Lambda Scorpii on the Feburary 17th, 2005 flyby. Notice that Lambda Scorpii passes behind Enceladus well above the south pole. The next occultation, of gamma Orionis (Bellatrix), occurred during the third and closest flyby on July 14th, 2005. This time, Bellatrix crossed behind the moon very near its south pole and emerged near the equator (shown in C and D).
This figure shows the spectrum of Bellatrix (blue line) along with the spectrum of light from the star seen through the plume of material near the south pole (red line). Note that prior to this detection, it was not known that Enceladus had any sort of atmosphere, even a temporary one. So the detection of absorption of the light from Bellatrix indicated that something must be happening around Enceladus.
The ratio of the red and blue lines in the previous figure are plotted in this graph as the thin solid line. Overlain on that curve as a darker solid line is the absorption spectrum of water. The water absorption spectrum explains the bulk of the total absorption seen near the south pole of Enceladus. Finer fluctuations are due to a number of a factors including the presence of other chemical species in smaller concentrations.
During the same flyby that UVIS was observing the occultation of Bellatrix by Enceladus, the INMS instrument detected something entirely unexpected: a sudden increase in particles near the south pole and surface of Enceladus. The INMS is, as its name says, a Mass Spectrometer (see this synopsis on the Huygens probe for an explanation of a similar instrument, the GCMS) that is capable of detected both ionized and neutral particles. The INMS is capable of detecting a wide range of chemicals including water, carbon dioxide, nitrogen, carbon monoxide, ammonia, and various hydrocarbons. It detected all of those compounds, some in very small quantities, in Enceladus’ plume.
The figure on the right illustrates how the density of water molecules detected by INMS changed as Cassini flew by on July 14th. A similar plume of dust was detected on the same approach using Cassini’s Cosmic Dust Analyzer (CDA). Notice that the peak of the CDA and INMS-Water plumes are offset slightly. This may indicate that the source of each plume is slightly different, or that the path between a common source and the detector differed for the dust and water. Also, notice that the peak of the water plume occurs very near to the south pole. This is strong evidence that the plume is originating from some sort of volcanic or vapor-geyser activity in that region. Combining this observation with those from UVIS and infrared maps of the surface makes a compelling case the the tiger stripes on Enceladus’ surface are the source of the plume. This, and the relatively frigid temperatures, led mission scientists to dub this plume “Cold Faithful.”
Context
This raft of discoveries about Enceladus are important for a number of reasons. First, they provide an explanation for a key observation about Saturn’s E-Ring. Second, Encladus has now become only the third planetary body whose volcanic activity has been directly observed from space (Earth, Io, and Enceladus are now on the list). Third, the heat output from that geological activity is very likely enough to ensure a body of liquid water at Enceladus’ south pole; again the list of moons or planets thought to have liquid water is quite short (Earth, Mars, Europa, Enceladus).
Sustained geologic (and volcanic) activity requires only one thing, heat. Larger planets at least as large as Venus (and maybe as small as Mars) have two long-term heat sources: 1) when the planet coalesces a tremendous amount of heat is released because of the decrease in potential energy of the grains of material from their diffuse spread-out state to the planet-bound one, 2) each body has a fixed amount of radioactive isotopes that decay and give off heat over millions to billions of years. Smaller moons, like Enceladus, lose their initial gravitationally-released heat rapidly, but they have a potential additional source heat from the tidal motions caused by their parent planets. Our Moon, for instance, seems to possess a liquid core largely because of tidal heating from the Earth. Europa probably has a global liquid ocean thanks to Jupiter’s massive tidal pull. Io is flagrantly volcanic for the same reason.
Sustained sources of heat means that water can remain liquid at depth on at least 4 planetary bodies in our solar system (again, Earth, Mars, Europa, Enceladus). Liquid water is a key ingredient in our form of life, and it may be a key ingredient in all life because of its unique properties. Europa and Enceladus are too far from the Sun for photo-dependent life to emerge, but chemically-dependent (no double-entendre intended) life probably could develop there. So now the search for life in our solar system can expand to Enceladus.
I have not yet heard any mention of such a mission in planning, but it would seem to me that searching for life on Enceladus is far simpler than doing so on Europa. After all, the “Cold Faithful” geyser system would eject not only liquid water but any organisms thriving there. So, send a craft to enter orbit around Enceladus and pass through that geyser thousands of times with a suite of life-detection instruments. This mission would be cheap and fast; I’m sure we will hear news of this idea from NASA very soon!
'Boom Blox' for Wii
EA unveils Spielberg's 'Boom Blox' for Wii
It's been a long time coming, but we finally have some actual details about the first game to emerge from the partnership between Steven Spielberg and Electronic Arts.
Known as Boom Blox, the game, which will be available in May only on the Wii, is from EA's casual games unit.
It will have more than 300 levels, "a cast of over thirty wacky characters" and seems to be built around letting players take on "Blox-laying chickens or...baseball-throwing monkeys" or cartoonlike grim reapers in tiki, medieval, frontier, or haunted themed settings.
EA has never said a lot about the Spielberg partnership beyond the fact that the director would be spending occasional time at the company's Los Angeles studio. It's also never been entirely clear exactly how involved Spielberg has been in the creation of the games, or how much involvement he'll have going forward. EA has said there would be at least three games under the terms of a deal first made public in 2005.
Last summer, Newsweek published a story describing the game that is now known as Boom Blox as blending "the creativity of the building-blocks game 'Jenga' with the charm of a Saturday-morning cartoon."
Based on what EA said Wednesday, that seems about right.
Newsweek also wrote at the time that the second game in the EA/Spielberg partnership was code-named "LMNO" and would be released for the Xbox 360 and PlayStation 3 consoles. The magazine said at the time the game would be "North by Northwest meets E.T.--if E.T. were female, grown up and, um, hot."
Nothing is yet known about the third game planned for the partnership.
One thing that hasn't been discussed is how EA will market these games. For instance, will their retail boxes mention Spielberg directly, and if so, how prominently?
It does seem like putting the first game out for the Wii is a good idea, what with the runaway success of that console and EA's need for big new hits.
Another smart move is switching consoles for the second game, because Spielberg brings unparalleled name recognition and even if Boom Blox flops, the audience for the second game will likely be quite different and unaffected by what happens with the first.
But if Boom Blox is a hit, it can only help everyone involved.
Still, because little is known about how much influence Spielberg has had on these games, it's very hard to know if he's a full partner in the initiative or if he's just lending his name to the titles. It is hard to imagine the latter, since Spielberg probably isn't in dire need of the money he's likely to get out of the deal. More likely, he felt like he had some story-telling expertise to lend EA and a love of video games, a medium that he hasn't dabbled much in before.
Update: It does occur to me, however, that everyone involved in the Spielberg/EA project, let alone anyone who cares about Spielberg's legacy, would probably like to see Boom Blox and its successors do a whole lot better than one video game project he was--at least tangentially--involved in previously.
For those that don't remember, the 1982 Atari 2600 game, E.T.: The Extra-Terrestrial, based, obviously on Spielberg's smash-hit film of the same name, didn't quite do as well as the movie.
In fact, according to Wikipedia, the game was a flop of universal proportions, known by many as one of the biggest "commercial failures in video game history."
Of course, this was a very different situation. For one, the E.T. game was based on an existing franchise. For two, it seems as though Spielberg wasn't hands-on with the 1982 game in the way he is with the EA titles.
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EA and Steven Spielberg Reveal BOOM BLOX
A must-have Wiigame for Summer 2008 is on its way! EA's Casual Entertainment Label today announced BOOM BLOX ,the first game developed in collaboration between EA and director and producer, Steven Spielberg. This high-energy game features over three hundred levels, a variety of activities, a cast of over thirty wacky characters, and an easy-to-use in-game editor that allows players to express their creativity. BOOM BLOX will be available in May 2008 for the Wiifrom Nintendo.
"I am a gamer myself, and I really wanted to create a video game that I could play with my kids," said Steven Spielberg. "BOOM BLOX features an enormous amount of fun challenges and cool scenarios for your kids to solve or for you to master together."
Fun for kids and the entire family, BOOM BLOX offers action-packed interactive activities that takes Wii play to a new level of creativity and fun with single player, co-op, and versus gameplay. Players can explore the visceral gameplay -- perfectly suited for the Wii's interactivity -- that keeps them destroying their way through brain-twisting challenges. They can interact with entertaining characters such as the Blox-laying chickens or the baseball throwing monkeys, who bring personality to the Tiki, Medieval, Frontier, and Haunted themed environments. Additionally, players can remix any level of the game in Create Mode using props, blocks, or characters that have been unlocked during the game. Players can also virtually build anything they can dream up. Plus, their designs can then be shared with friends or used to challenge others to solve their newly created puzzle via WiiConnect24.
"We developed BOOM BLOX with endless combinations of gameplay in mind," explains Louis Castle, Executive Producer. "With over three hundred levels, built upon a full real-time physics model, your experience can be as easy or difficult as you want it to be -- there really is something for everyone to enjoy."
"My inspiration for this game came while I was playing the Wii for the first time," added Spielberg. "From the initial concept to what the game is today, it's always been built around the innovations the Wii brings to playing games. BOOM BLOX plays on the enjoyment of building and knocking down blocks, something that can appeal innately to kids and adults of all ages."
Developed at EA Los Angeles under the EA Casual Entertainment Label, BOOM BLOX has not yet been rated by the ESRB and PEGI. For more information or to download artwork, visit http://www.BOOMBLOX.ea.com.
BOOM BLOX is also in production for mobile phones and will be widely available this Spring. The mobile version puts innovative BOOM BLOX gameplay on phones everywhere -- delivering engaging, fun, and groundbreaking action. For the first time in a mobile game, players will be able to create custom levels and share them with their friends directly from the phone, enjoying a rich, interactive community experience. For information regarding mobile phone carrier availability, visit http://www.eamobile.com.
Hidden Art Could Be Revealed By New Terahertz Device
Like X-rays let doctors see the bones beneath our skin, "T-rays" could let art historians see murals hidden beneath coats of plaster or paint in centuries-old buildings, University of Michigan engineering researchers say.
T-rays, pulses of terahertz radiation, could also illuminate penciled sketches under paintings on canvas without harming the artwork, the researchers say. Current methods of imaging underdrawings can't detect certain art materials such as graphite or sanguine, a red chalk that some of the masters are believed to have used.
The team of researchers, which includes scientists at the Louvre Museum, Picometrix, LLC and U-M, used terahertz imaging to detect colored paints and a graphite drawing of a butterfly through 4 mm of plaster. They believe their technique is capable of seeing even deeper.
In March, the scientists will take their equipment to France to help archaeologists examine a mural they discovered recently behind five layers of plaster in a 12th century church.
"It's ideal that the method of evaluation for historical artifacts such as frescoes and mural paintings, which are typically an inherent part of a building's infrastructure, be non-destructive, non-invasive, precise and applicable on site. Current technologies may satisfy one or more of these requirements, but we believe our new technique can satisfy all of them," said John Whitaker, an author of the paper who is a research scientist and adjunct professor in the Department of Electrical Engineering and Computer Science at U-M.
Terahertz imaging can reveal depth and detail that other techniques cannot, Whitaker said. And it's not potentially harmful like X-ray imaging because terahertz radiation is non-ionizing. Its rays don't have enough energy to knock electrons off atoms, forming charged particles and causing damage, like X-rays do.
While terahertz radiation is all around us in nature, it has been difficult to produce in a lab because it falls between the capabilities of electronic devices and lasers.
"Terahertz is a strange range in the electromagnetic spectrum because it's quasi-optical. It is light, but it isn't," said Bianca Jackson, first author of the paper who is a doctoral student in applied physics.
The device used for this research is a hybrid between electronics and lasers. It was developed by the Ann-Arbor based company Picometrix. It's called the T-Ray™ system, and it uses pulses from an ultra-fast laser to excite a semiconductor antenna, which in turn emits pulses of terahertz radiation.
The rays permeate the plaster, and some reflect back when there is a change in the material. When they bounce back and how much energy they retain depends on the material they hit. Different colors of paint, or the presence of graphite, for example, cause tell-tale differences in the amount of energy in the returning waves. A receiver measures this energy, and the scientists can use the data to produce an image of what lies beneath, Jackson explained.
A similar device made by Picometrix is used routinely to examine the foam on the space shuttle's fuel tanks for underlying damage, said Irl Duling, director of terahertz business development at Picometrix and an author of the paper. This paper discusses a new application, rather than a new device.
Gèrard Mourou, a U-M electrical engineering professor emeritus, said he believes this technique will be especially useful in Europe, where historic regime changes often resulted in artworks being plastered or painted over. This was common in places of worship, some of which switched from churches to mosques and vice versa over the centuries.
"In France alone, you have 100,000 churches," Mourou said. "In many of these places, we know there is something hidden. It has already been written about. This is a quick way to find it."
And Leonardo DaVinci's "The Battle of Anghiari," for example, is believed to lurk beneath other frescos at the Palazzo Vecchio in Florence, Italy, Mourou said.
The paper "Terahertz imaging for non-destructive evaluation of mural paintings," is published in the February edition of Optics Communications.
Mourou is the A. D. Moore Distinguished University Professor Emeritus of Electrical Engineering and Computer Science. He currently holds a position at the Laboratoire d'Optique Appliquèe. Other authors are: Steven Williamson of Picometrix; Marie Mourou, a U-M undergraduate student; and Michel Menu, of the Center for Research and Restoration at The Louvre Museum.
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Scientists develop new terahertz material
Researchers at Los Alamos National Laboratory have created a device for manipulating terahertz (THz) radiation. The device could be the basis for novel electronics and photonics applications ranging from new imaging methods to advanced communication technologies. The THz range of the electromagnetic spectrum lies between the infrared and microwave wavelengths.
In research published in the journal Nature, Los Alamos scientist Hou-Tong Chen and his colleagues explain how metamaterials (artificial materials with properties derived from their sub-wavelength structures instead of their compositions) can be designed to efficiently control THz waves.
According to Chen, "devices that generate and detect THz radiation are already in development, but techniques to actually control the waves are lagging behind. This is the next logical step in the development of terahertz technologies for wider electronics and photonics applications."
Like microwaves, terahertz radiation has the ability to penetrate a wide variety of non-conducting materials like paper, plastics, wood, and ceramics. Because it can "see" through plastics and cardboard, it might also be used in manufacturing to inspect packaged objects for quality control or process monitoring. THz radiation is sensitive to the water content, which means it might be used to detect differences in body tissue density. Because terahertz radiation is non-ionizing, it does not damage DNA like X-rays and might someday be used as a safer alternative for certain types of medical and dental imaging. Non-ionizing means the radiation does not have enough energy to convert electrically neutral atoms into ions by knocking an atom's electron from its orbit.
To create their device, Chen and his colleagues used micro-fabrication processes to lay down an array of gold metamaterial structures over a semiconductor substrate. An applied voltage between the substrate and the metamaterial enables the device to modulate the intensity of THz waves by up to 50 percent. The experimental demonstration of the device exceeds the performance of existing electrical THz modulators and the team hopes to further improve the device's performance in coming months. news, tec,
In addition to Chen, other members of the THz device development team include Willie Padilla, formerly of Los Alamos and now with Boston College, Richard Averitt, formerly of Los Alamos and now with Boston University, Antoinette Taylor from Los Alamos, and Joshua Zide and Arthur Gossard from the University of California, Santa Barbara. The research was supported by Laboratory Directed Research and Development funds and the Center for Integrated Nanotechnologies, a DOE/Office of Science Nanoscale Research Center.
The ,space shuttle Atlantis has a 70% chance of getting rained out,
Weather outlook Thursday's launch of the space shuttle Atlantis has a 70% chance of getting rained out, NASA mission managers said this morning.
A cold front moving across the U.S. this week unleashed dozens of tornadoes in the mid-South late Tuesday evening and continues to churn up thunderstorms. NASA doesn't expect a twister to botch their 2:45 p.m. ET launch opportunity on Thursday, but the threat of a thunderstorm, showers or thick cloud cover has lowered launch expectations from 40% to 30%.
Jeff Spaulding, NASA test director, said the best case scenario is if inclement conditions suddenly clear up before launch time.
"We always hope for that," Spaulding said. "As we all know, weather in Florida changes very rapidly. Things may improve or improve enough to get us the ability to get off the ground. The worst case would be if ... we'd have to try a different day."
Showers concern NASA because rain can damage the thermal protection shield of Atlantis during its high-speed launch. Heavy cloud cover is also problematic, Winters noted, because visibility of the shuttle as it launches can be obscured and pose a threat to public safety.
Should unfavorable conditions push the agency to scrub its launch in the early tomorrow morning, mission managers will aim for a 2:19 p.m. ET attempt on Friday. The chance of getting Atlantis into orbit then has also been lowered, from 40% to 20%, because of the potential for lingering rain showers.
As NASA crosses its fingers for a break in bad weather tomorrow, technicians continue to prepare Atlantis for its big moment.
The 100-ton orbiter's power-producing fuel cells have been filled and will be activated later this evening, following the retraction of launch Pad 39A's 13-story rotating service structure (RSS). The moveable scaffolding helps technicians service and inspect vital areas of the space shuttle after it is rolled out to the launch pad. Once the RSS is rolled back, it will reveal the freshly prepared Atlantis spacecraft.
The seven astronauts of the STS-122 mission have also been making final preparations for their space shot.
The 11-day mission, led by Navy captain Stephen Frick, is slated to deliver the European Space Agency's (ESA) 10.3-ton Columbus laboratory to the International Space Station (ISS). Pilot Alan Poindexter, mission specialists Leland Melvin, Rex Walheim and Stanley Love, and ESA astronauts Leopold Eyharts and Hans Schlegel will join Frick on the mission.
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Atlantis Waits On The Weather
Space shuttle Atlantis sits ready on launch pad 39A at the Kennedy Space Center in Cape Canaveral.
Not wind nor rain nor hail stops the U.S. Postal Service, but they do frustrate the people trying to launch space shuttles.
A weather front moving through Florida could put the brakes on Thursday's planned 2:47 p.m. liftoff of Atlantis, when storm clouds are expected to linger around Kennedy Space Center.
Air Force meteorologists give only a 30 percent chance of favorable conditions. If NASA begins pumping 500,000 gallons of fuel into the giant external tank about 5:30 a.m., the countdown will continue.
The seven astronauts were supposed to blast off in December on an 11-day mission to the International Space Station, but faulty fuel sensors forced lengthy troubleshooting and repairs on the pad. Now, with the shuttle given a clean bill of health, it's a matter of waiting out the weather.
If all goes well, Atlantis will take into orbit a giant science lab called Columbus, built by the European Space Agency. The 10-ton cylinder houses nearly a dozen science "racks" where astronauts will do experiments in near zero-gravity.
"Everything is ready to go," said Clare Mattok, a spokeswoman for the ESA. "Time really isn't a problem because we could wait on the pad until the end of March. This mission has been a long time coming, so a few extra weeks of delays won't make a difference."
But the National Aeronautics and Space Administration doesn't have as much wiggle room as it did in past years. The shuttle fleet is on target for retirement in 2010, and with less than a dozen missions left, the agency must complete as much of the space station as possible, and make repairs on the Hubble Space Telescope.
Atlantis' crew consists of commander Stephen Frick; pilot Alan Poindexter; mission specialists Leland Melvin, Rex Walheim and Stanley Love; and European Space Agency astronauts Hans Schlegel and Leopold Eyharts. Eyharts will remain on the space station, replacing Dan Tani, who will come home aboard Atlantis.
Water has some amazing properties.
Rain drops falling on still water
New Clue In The Mystery Of Glassy Water
Water has some amazing properties. It is the only natural substance found in all three states -- solid, liquid and gas -- within the range of natural Earth temperatures. Its solid form is less dense than its liquid form, which is why ice floats. It can absorb a great deal of heat without getting hot, has very high surface tension (helping it move through roots and capillaries -- vital to maintaining life on Earth) and is virtually incompressible.
A less commonly known distinction of water, but one of great interest to physical chemists, is its odd behavior at its transition to the glassy phase. The "glassy state" is a sub-state of matter -- glassy water and ice, for example, are chemically identical and have the same state (solid), but have a different structure. Put another way, ice is crystalline, whereas glass is, well, chunky. As water makes the transition to its glassy state, it behaves very oddly, a fact that has baffled scientists.
Arizona State University Regents Professor C. Austen Angell has found a vital clue that helps explain water's bizarre behavior at the glass transition and, along the way, gained important insights into phases of liquid water as well. His research is published in the Feb. 1, 2008 issue of the journal Science.
"We know a lot about glasses that form from ordinary silicates, sugars and metals," Angell says. "They're making golf clubs out of glassy metals these days. But how important is the glassy state of water" And what can it tell us about ordinary water, which is such an anomalous liquid?"
Most glassy forms of matter experience a gradual increase in heat capacity -- the amount of energy it takes to heat a sample by one degree Kelvin -- until a key transition point is reached. At that point (called the "glass temperature"), these materials suddenly up-jump to a new, 100 percent higher, heat capacity zone and change from a solid to very viscous liquid phase -- as if a solid brick of cold honey were heated and suddenly became a sticky liquid again. This occurs even in solutions in which water is the chief component.
In pure water, however, something quite different happens. As cold, glassy water is heated, its heat capacity barely changes until about 136 K (-215 F), where it begins to increase slightly. Then, abruptly at 150 K (-190 F), it crystallizes and stops being glassy. Approached from the other direction, supercooling water produces a similarly odd effect: Heat capacity remains constant as the water cools until around 250 K (-10 F), when it begins to increase very rapidly with decreasing temperature.
Angell wanted to know what was transpiring in the "no man's land" between 150 and 250 K (-190 and -10 F). Where, he wondered, was the "real" glass transition for glassy water?
He solved the problem by looking at the behavior of both supercooled water and "nanoconfined" glassy ice. Nanoconfined water is water that has been squeezed into pores with a diameter of about 20 angstroms, or 20 hundred-millionths of a meter (roughly five times the scale of atoms and chemical bonds). Using the behavior of water in these states and combining it with a hypothetical behavior of bulk water deduced using the laws of thermodynamics, he was able to bracket the possible heat capacity of water in the "no man's land" and come up with a novel cooperative transition to explain the substance's odd behavior.
"Water's heat capacity suddenly goes crazy near this transition and, before we can see what is happening, it crystallizes," Angell says. "One trick for finding out what is going on in there is to put the water in a confinement -- to make it nanoscopic so that it forgets how to crystallize. We see the same behavior but with no data gap."
According to Angell, water does not behave like the usual glass formers and therefore lacks the characteristic heat-capacity jump (glass transition) to the glassy phase; instead, because of its unusual hydrogen bond network, it behaves as if it is in a crystalline phase, making what is known as an "order-disorder transition." This sucks out all of the heat capacity at temperatures around 220 K and explains why the glass transition in water (near 136 K) is so undramatic compared to other substances.
It also gave Angell an idea for a new scenario to explain the odd behavior of supercooled water, one that is compatible with observed behavior but does not require a critical point.
"I wanted to find the answer to the puzzle of what was happening in 'no man's land,'" Angell says. "And so I worked up from the glassy state and nanoconfinement."
"In the end, we say, 'Well that that's not what bulk water would do -- that's been thrust upon it by making it so tiny,'" he explains. "But nevertheless it's an important part of the picture and it supports the conclusion that we've got a different sort of thermodynamics in water than we have in any of these other molecular glass-forming liquids."
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Weird Water: Discovery Challenges Long-held Beliefs About Water's Special Properties
Water has some amazing properties. It is the only natural substance found in all three states -- solid, liquid and gas -- within the range of natural Earth temperatures. Its solid form is less dense than its liquid form, which is why ice floats. It can absorb a great deal of heat without getting hot, has very high surface tension (helping it move through roots and capillaries -- vital to maintaining life on Earth) and is virtually incompressible.
The simple fact that water expands when it freezes -- an effect known to anyone whose plumbing has burst in winter -- is just the beginning of a long list of special characteristics. (Most liquids contract when they freeze.)
That is why chemical engineer Pablo Debenedetti and collaborators at three other institutions were surprised to find a highly simplified model molecule that behaves in much the same way as water, a discovery that upends long-held beliefs about what makes water so special.
"The conventional wisdom is that water is unique," said Debenedetti, the Class of 1950 Professor in Engineering and Applied Science. "And here we have a very simple model that displays behaviors that are very hard to get in anything but water. It forces you to rethink what is unique about water."
While their water imitator is hypothetical -- it was created with computer software that is commonly used for simulating interactions between molecules -- the researchers' discovery may ultimately have implications for industrial or pharmaceutical research. "I would be very interested to see if experimentalists could create colloids (small particles suspended in liquid) that exhibit the water-like properties we observed in our simulations," Debenedetti said. Such laboratory creations might be useful in controlling the self-assembly of complex biomolecules or detergents and other surfactants. .
More fundamentally, the research raises questions about why oil and water don't mix, because the simulated molecule repels oil as water does, but without the delicate interactions between hydrogen and oxygen that are thought to give water much of its special behavior.
The discovery builds on an earlier advance by the same researchers. It had previously been shown that simple molecules can show some water-like features. In 2006, the collaborators published a paper showing that they could induce water-like peculiarities by adjusting the distance at which pairs of particles start to repel each other. Like water, their simulated substance expanded when cooled and became more slippery when pressurized. That finding led them to investigate more closely. They decided to look at how their simulated molecule acts as a solvent -- that is, how it behaves when other materials are dissolved into it -- because water's behavior as a solvent is also unique.
In their current paper, they simulated the introduction of oily materials into their imitator and showed that it had the same oil-water repulsion as real water across a range of temperatures. They also simulated dissolving oily polymers into their substance and, again, found water-like behavior. In particular, the polymers swelled not only when the "water" was heated, but also when it was super-cooled, which is one defining characteristic of real water. Proteins with oily interiors also behave in this way.
In real water, these special behaviors are thought to arise from water's structure -- two hydrogen atoms attached to an oxygen atom. The arrangement of electrical charges causes water molecules to twist and stick to each other in complex ways.
To create their simulation, the researchers ignored these complexities. They specified just two properties: the distance at which two converging particles start to repel each other and the distance at which they actually collide like billiard balls. Their particles could be made of anything -- plastic beads, for example -- and so long as the ratio between these two distances was correct (7:4), then they would display many of the same characteristics as water.
"This model is so simple it is almost a caricature," Debenedetti said. "And yet it has these very special properties. To show that you can have oil-water repulsion without hydrogen bonds is quite interesting."
Debenedetti noted that their particles differ from water in key aspects. When it freezes, for example, the crystals do not look anything like ice. For that reason, the research should not be viewed as leading toward a "water substitute."
As a next step, Debenedetti said he would like to see if experimentalists could create particles that have the same simple specifications as their model and see if their behavior matches the computer simulation.
The researchers published their findings Dec. 12 in the Proceedings of the National Academy of Sciences. The team also included lead author Sergey V. Buldyrev of Yeshiva University, Pradeep Kumar and H. Eugene Stanley of Boston University, and Peter J. Rossky of the University of Texas. The research was funded by the National Science Foundation through a grant shared by Debenedetti, Rossky and Stanley.
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